Repository logo
 

Design & modeling of phase transforming ultra-high temperature metal ceramic multilayer composites

dc.contributor.authorStotts, John Carter, author
dc.contributor.authorWeinberger, Christopher R., advisor
dc.contributor.authorGelfand, Martin, committee member
dc.contributor.authorMa, Kaka, committee member
dc.contributor.authorSambur, Justin, committee member
dc.date.accessioned2025-06-02T15:21:14Z
dc.date.available2025-06-02T15:21:14Z
dc.date.issued2025
dc.description.abstractUltra-high temperature ceramics are a class of materials that have found use in high-temperature structural applications due to their high melting temperatures and excellent high-temperature mechanical properties. Although this class of materials is well-suited to these applications at high temperature, they suffer from a low fracture toughness at ambient temperatures where component fabrication and assembly takes place. Thus, during the fabrication and assembly process these materials are highly susceptible to catastrophic brittle failure. In this work, we introduce a novel type of composite that significantly improves the low-temperature fracture toughness without sacrificing the excellent high-temperature properties of the ultra-high temperature ceramics. These novel composites are an innovative approach to metal-ceramic multilayer composites, with the unique ability undergo a phase transformation in the metal layers that results in their disappearance, leaving a single-phase ultra-high temperature ceramic after annealing. In this work, we endeavored to model this phase transformation process and characterize the performance of the composite in order to optimize the material selection and design of the composite. To achieve this goal, we determined the phase transformation time of composites using Finite Element Method simulations and constructed more general, coarse-grained, models of the phase transformation kinetics and toughening. The key to enabling the phase transformation in these composites is to choose group IV transition metal carbides or nitrides and group V transition metal carbides for the ceramic layers of the composite. This group of materials possess a wide range of homogeneity with respect to carbon/nitrogen content in their monocarbide/nitride phases. Additionally, the phase transformation from metal to ceramic in these materials is controlled by the diffusion of the nonmetal atom (carbon/nitrogen) and results in ceramic layer growth with strong adhesion between layers. Thus, a composite can be constructed with a 'frozen-in' non-equilibrium microstructure containing alternating layers of metal and ceramic and be made to transform simply by increasing the temperature, i.e. annealing. Furthermore, this work contains an investigation into the kinetics of carbon diffusion in substoichiometric titanium carbide. This investigation, motivated by an open question in the literature posed by Sarian in 1968, used a computational approach comprised of Monte Carlo, kinetic Monte Carlo, and Density Functional Theory simulations in order to determine the interconnection of diffusion and vacancy-ordered phases. The investigation was multi-pronged, beginning with simulations on a square lattice and then being extended to three-dimension simulations of the titanium carbide carbon-vacancy sublattice.
dc.format.mediumborn digital
dc.format.mediumdoctoral dissertations
dc.identifierStotts_colostate_0053A_18847.pdf
dc.identifier.urihttps://hdl.handle.net/10217/241041
dc.languageEnglish
dc.language.isoeng
dc.publisherColorado State University. Libraries
dc.relation.ispartof2020-
dc.rightsCopyright and other restrictions may apply. User is responsible for compliance with all applicable laws. For information about copyright law, please see https://libguides.colostate.edu/copyright.
dc.subjectdiffusion
dc.subjecthypersonics
dc.subjectultra-high temperature ceramics
dc.subjecthigh temperature materials
dc.subjectcomposites
dc.subjectphase transformations
dc.titleDesign & modeling of phase transforming ultra-high temperature metal ceramic multilayer composites
dc.typeText
dcterms.rights.dplaThis Item is protected by copyright and/or related rights (https://rightsstatements.org/vocab/InC/1.0/). You are free to use this Item in any way that is permitted by the copyright and related rights legislation that applies to your use. For other uses you need to obtain permission from the rights-holder(s).
thesis.degree.disciplineMaterials Science and Engineering
thesis.degree.grantorColorado State University
thesis.degree.levelDoctoral
thesis.degree.nameDoctor of Philosophy (Ph.D.)

Files

Original bundle

Now showing 1 - 1 of 1
Loading...
Thumbnail Image
Name:
Stotts_colostate_0053A_18847.pdf
Size:
14.33 MB
Format:
Adobe Portable Document Format