Mountain Scholar
Mountain Scholar is an open access repository service that collects, preserves, and provides access to digitized library collections and other scholarly and creative works from several academic entities within the state of Colorado.
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Chemistry, availability and mobility of molybdenum in Colorado soils, The
The purpose of this study was to investigate the impact of molybdenum contamination in irrigation water on soils and pastures in Colorado. The chemistry, availability and mobility of Mo was studied in the laboratory, ... -
Concise enantioselective synthesis of (+)-FR66070 and (+)-FR900482 and the synthesis and biochemical studies of a photo-triggered FR900482 mitosene progenitor
The total synthesis of the natural products (+)-FR66979 and (+)-FR900482 is presented. The synthesis features a novel dimethyldioxirane-mediated reaction for construction of the hydroxylamine hemiketal functionality and ... -
Studies on the total synthesis of putative intermediates in the biosynthesis of taxol
The exploration of several strategies for the synthesis of taxoids useful for studying the biosynthesis of taxol is presented. The approaches described include attempts to access the taxane carbon skeleton through closure ... -
Asymmetric total syntheses of (+)- and (-)-spirotryprostatins A and B
The first published total synthesis of (+)- and (-)-spirotryprostatin B is presented. The synthesis features an asymmetric azomethine ylide [1,3]-dipolar cycloaddition reaction. Additionally, a Barton-modified Hunsdiecker ... -
Asymmetric synthesis of (2S,3R)-capreomycidine and the total synthesis of capreomycin IB, The
An efficient and asymmetric synthesis of the non-proteinogenic amino acid (2S,3R)-capreomycidine is presented. The synthesis features a novel aluminum enolate-aldimine reaction with a chiral glycinate, which sets both ...
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