Dataset associated with "Particle Size Distribution Dynamics Can Help Constrain the Phase State of Secondary Organic Aerosol"
Date
2021
Authors
He, Yicong
Akherati, Ali
Nah, Theodora
Nga, Ng
Garofalo, Lauren
Farmer, Delphine
Shiraiwa, Manabu
Zaveri, Rahul
Christopher, Cappa
Pierce, Jeff
Journal Title
Journal ISSN
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Abstract
Particle phase state is a property of atmospheric aerosols that has important implications for the formation, evolution, and gas/particle partitioning of secondary organic aerosol (SOA). In this work, we use a size-resolved chemistry and microphysics model (SOM-TOMAS), updated to include an explicit treatment of particle phase state, to constrain the bulk diffusion coefficient (Db) of SOA produced from alpha-pinene ozonolysis. By leveraging data from laboratory experiments performed in the absence of a seed and under dry conditions, we find that the Db for SOA can be constrained (1-5 ×10^-15 cm^2 s^-1 in these experiments) by simultaneously reproducing the time-varying SOA mass concentrations and the evolution of the particle size distribution. Another version of our model that used the predicted SOA composition to calculate the glass transition temperature, viscosity, and, ultimately, Db (~10-15 cm^2 s^-1) of the SOA was able to reproduce the mass and size distribution measurements when we included oligomer formation (oligomers accounted for about a fifth of the SOA mass). Our work highlights the potential of a size-resolved SOA model to constrain the particle phase state of SOA by utilizing historical measurements of the evolution of the particle size distribution.
Description
This dataset contains all data used to make the figures and the code of the SOM-TOMAS model.
Department of Mechanical Engineering
Department of Atmospheric Science
Department of Chemistry
Department of Mechanical Engineering
Department of Atmospheric Science
Department of Chemistry
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Associated Publications
Yicong He, Ali Akherati, Theodora Nah, Nga L. Ng, Lauren A. Garofalo, Delphine K. Farmer, Manabu Shiraiwa, Rahul A. Zaveri, Christopher D. Cappa, Jeffrey R. Pierce, and Shantanu H. Jathar. Particle Size Distribution Dynamics Can Help Constrain the Phase State of Secondary Organic Aerosol. Environ. Sci. Technol. 2021, 55, 1466-1476. https://doi.org/10.1021/acs.est.0c05796