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Department of Statistics

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https://hdl.handle.net/10217/100518
These digital collections include theses, dissertations, and datasets from the Department of Statistics. Due to departmental name changes, materials from the following historical department are also included here: Mathematics and Statistics.

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Browsing Department of Statistics by Subject "air quality"

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    Dataset associated with "Laboratory evaluation of low-cost PurpleAir PM monitors and in-field correction using co-located portable filter samplers"
    (Colorado State University. Libraries, 2019) Tryner, Jessica; L'Orange, Christian; Mehaffy, John; Miller-Lionberg, Daniel; Hofstetter, Josephine C.; Wilson, Ander; Volckens, John
    Low-cost aerosol monitors can provide more spatially- and temporally-resolved data on ambient fine particulate matter (PM2.5) concentrations than are typically available from regulatory monitoring networks; however, low-cost monitors—which do not measure PM2.5 mass directly and tend to be sensitive to variations in particle size and refractive index—sometimes produce inaccurate concentration estimates. We investigated laboratory- and field-based approaches for calibrating low-cost PurpleAir monitors against gravimetric filter samples. First, we investigated the linearity of the PurpleAir response to NIST Urban PM and derived a laboratory-based gravimetric correction factor. Then, we co-located PurpleAir monitors with portable filter samplers at 15 outdoor sites spanning a 3×3-km area in Fort Collins, CO, USA. We evaluated whether PM2.5 correction factors derived from periodic co-locations with portable filter samplers improved the accuracy of PurpleAir monitors (relative to reference filter samplers operated at 16.7 L/min). We also compared 72-hour average PM2.5 concentrations measured using portable and reference filter samplers. Both before and after field deployment, the coefficient of determination for a linear model relating NIST Urban PM concentrations measured by a tapered element oscillating microbalance and the PurpleAir monitors (PM2.5 ATM) was 0.99; however, an F-test identified a significant lack of fit between the model and the data. The laboratory-based correction factor did not translate to the field. Correction factors derived in the field from monthly, weekly, semi-weekly, and concurrent co-locations with portable filter samplers increased the fraction of 72-hour average PurpleAir PM2.5 concentrations that were within 20% of the reference concentrations from 15% (for uncorrected measurements) to 45%, 59%, 56%, and 70%, respectively. Furthermore, 72-hour average PM2.5 concentrations measured using portable and reference filter samplers agreed (bias ≤ 20% for 71% of samples). These results demonstrate that periodic co-location with portable filter samplers can improve the accuracy of 72-hour average PM2.5 concentrations reported by PurpleAir monitors.