Browsing by Subject "(+)-K252a"

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Part I, The total synthesis of (±)-securinine and (±)-allosecurinine and synthetic strategies for a second generation synthesis of the securinega alkaloids and Part II, The use of (+)-K252a in the semi-synthesis of indolocarbazole natural products and novel analogs thereof

Author(s):Levine, Samantha Roslyn
Date Submitted:2014

In part I, the total syntheses of (±)-securinine ((±)-1.001) and (±)-allosecurinine ((±)-1.003) are described. The syntheses feature the use of a Rh-initiated O—H insertion/Claisen rearrangement/1,2-allyl migration, which ...