Taylor, Geoffrey Ryan, authorSale, Thomas, advisorMcWhorter, David, committee memberWarner, James, committee member2024-01-082024-01-082004https://hdl.handle.net/10217/237482Covers not scanned.Print version deaccessioned 2024.Petroleum liquids, commonly referred to as LNAPL's, have become a basic building block of modem society. Used as fuels, lubricants, solvents and chemical feed stocks, petroleum liquids have brought many conveniences to our lives. However, a small fraction of these liquids have been inadvertently released into the subsurface forming contiguous bodies of separate phase liquids. Resolving how to manage these releases hinges largely on the rate at which these bodies are moving. To that end, a number of techniques have been developed in an effort to measure the migration, or flow rate, of LNAPL in the subsurface. Many of the current methods require challenging and costly indirect measurements to estimate this migration. The purpose of this thesis is to explore a promising new method that directly measures the flow rate of LNAPL's, a method that builds on the tracer dilution technique used to measure the flow of groundwater. Traditional tracer dilution techniques measures the dilution of a tracer, placed into a well, to determine the flow rate of water through the well. The flow rate through the well is then used to calculate the flow rate of groundwater. The same theory applies to LNAPL's flowing through a well. Determining the potential of the tracer dilution technique to measure LNAPL flow through a well requires investigating the mathematics governing the tracer dilution technique. A first order dilution equation was adapted for LNAPL. A method to analyze the results in a dimensionless format was also developed because it provides a technique to determine when the data conforms to the assumptions of the dilution equation. The mathematics necessary to convert the flow rate of LNAPL through a well into common measures is also derived. Laboratory studies were conducted to verify the mathematics and to determine the applicability of the tracer dilution technique to measure LNAPL flow. At first, small scale experiments were used to visualize the dilution process and develop the technology necessary to conduct tracer dilution tests in LNAPL. A fluorescent dye, BSL 715, was selected as a tracer. A spectrometer and computer were used to measure and log the fluorescent intensity, which is a measure of the tracer concentration. A device to mix the tracer in the well without causing adverse dilution was also developed. A large tank study explored the tracer dilution technique using a typical range of LNAPL thicknesses and flow rates. The flow rates varied from 7.2 m3/m/yr to 0.035 m3/m/yr and the LNAPL thicknesses varied from 9cm to 24cm. The results of the large tank study demonstrated that the tracer dilution technique is an accurate and reliable method to measure the migration of petroleum liquids in the subsurface. The measured error tends to increase at lower flow rates but is insensitive to the LNAPL thickness. The results of the large tank study led to a field test at the former ChevronTexaco Refinery in Casper, WY. The tracer dilution method was deployed in two locations. The first location was near an active recovery well where the flow rate was expected to be high. The second test was conducted in a quiescent area where the flow rate was low. The first test, near the recovery well, measured a flow rate of 0.1 m3/m/yr to 0.3 m3/m/yr. The second test, in a quiescent area, indicated a flow rate of less then 0.005 m3/m/yr. In addition, opportunities for improving sensitivity and increasing the usefulness of the method were discovered. In all, the experiments have shown the tracer dilution technique to be an effective method to directly measure the in situ migration of petroleum liquids in the subsurface.masters thesesengCopyright and other restrictions may apply. User is responsible for compliance with all applicable laws. For information about copyright law, please see https://libguides.colostate.edu/copyright.SeepageGroundwater flowGroundwater -- PollutionText